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Q.

Calculate the pH of a solution obtained by mixing 200mL of 0.1MHCl with 800mL of 0.125MCH3COOHKa for CH3COOH=1.8×105

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answer is 1.6968.

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Detailed Solution

Concentration of HCl after mixing (c2) =200×0.1200+800=0.02 M

Concentration of CH3COOH after mixing (c1)= 800×0.125800+200=0.1M

H3O+ of mixture of weak acid and strong acid = c2+c22+4kac12

=0.02+0.022+4×1.8×10-5×0.12

on solving H3O+ = 2.01×10-2

pH = 2- log2.01 = 2 - 0.3032 = 1.6968

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Calculate the pH of a solution obtained by mixing 200mL of 0.1MHCl with 800mL of 0.125MCH3COOH. Ka for CH3COOH=1.8×10−5