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Q.

Calculate the potential of a half cell having reaction : Ag2S(s)+2e2Ag(S)+S2(aq) in a solution buffered at pH=3 and which is also saturated with 0.1MH2S(aq)
 [Given : KspAg2S=2×1049;Ka1Ka2=1.1×1021;EAg+/Ag0=0.8V

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a

1.18 V

b

0.19

c

-0.19V

d

-0.166 V

answer is D.

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Detailed Solution

Ka=Ka1Ka2=H2S2/H2S(1)Ksp=AgS2(2) from 1 \& 2Ag=4.264×1017MES2/AgS2S/Ag=EAg+/Ag0-0.0591nlog1[Ag+]E=0.80.05911log14.264×1017E=0.166

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