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Q.

Calculate the reversible potential of oxygen electrode in a solution of pH = 1, when the partial pressure of O2 is 10-2atm [Assume EO2/H2O0=1.23 V,vs SHE  at 1 atm and 25°C ]

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a

1.71V

b

1.112V

c

1.97V

d

1.19V

answer is C.

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Detailed Solution

O2+2H2O+4e-4OH- pH=1pOH=14-pHpOH=14-1pOH=13OH-=10-pOHOH-=10-13M EO2,H2O=EO2/H2O0-0.0591nlogOH-4PO2EO2/H2O=1.23 V-0.05914log10-13410-2EO2/H2O=1.23 V-0.05914log10-13410-2EO2/H2O=1.97 V

Therefore, the correct option is C

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