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Q.

Calculate the solubility of A2X3 in pure water, assuming that neither kind of ion reacts with water. The solubility product of A2X3,Ksp=1.1×10-23

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a

2.0×10-5 mol L-1

b

5.0×10-5 mol L-1

c

1.0×10-5 mol L-1

d

4.0×10-3 mol L-1

answer is C.

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Detailed Solution

A2X32A3++3X2-

Ksp=A3+2X2-3=1.1×10-23

 If S= solubility of A2X3, then 

A3+=2S;  X2-=3S

therefore, Ksp=(2S)2(3S)3

=(108)S5=1.1×10-23

Thus, S5=1×10-25

S=1.0×10-5 mol L

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