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Q.

Calculate the value of  ΔHo/kJ  for the following reaction using the listed thermochemical equations:
2C(s)+H2(g)C2H2(g)2C2H2(g)+5O2(g)4CO2(g)+2H2O(1)    ΔH0/kJ=2600kJC(s)+O2(g)CO2(g)      ΔH0/kJ=390kJ2H2(g)+O2(g)2H2O(1)    ΔH0/kJ=572kJ 

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a

+214

b

+234 

c

+184

d

+202

answer is D.

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Detailed Solution

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2  C2H2(g)+5  O2(g)4  CO2(g)+2  H2O(I)                   (i)                                                               ΔH0/kJ=2600kJC(s)+O2(g)CO2(g)                 ΔH0/kJ=390kJ        (ii)2  H2(g)+O2(g)2H2O(I)           ΔH0/kJ=572kJ     (iii)ΔrHfor2C(s)+H2(g)  C2H2         can  be  calculated  byΔrH=(1300)+2(390)+  ×(572)ΔrH=234

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