Q.

Calculate the volume of gas liberated at the anode at STP during the electrolysis of an aq.CuSO4 solution by a current of 1A passed for 16 minutes and 5 seconds.

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a

56mL

b

112mL

c

224mL

d

448mL

answer is B.

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Detailed Solution

CuSO4+H2O ele 2FCu+12O2+H2SO4 2F12 mole O2;Q=c×t=1×[16×60+5]=965 coul  2×96500 columbs 12×22.4 lit  965coulV=?  V=965×11.22×96500=0.056 lit =56ml

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Calculate the volume of gas liberated at the anode at STP during the electrolysis of an aq.CuSO4 solution by a current of 1A passed for 16 minutes and 5 seconds.