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Q.

Calculate the Hvaporization CH3COOH(l) in kJ/mol. Given data :

ΔHsolution KFCH3COOH(s) in glacial acetic acid3 kJ/mole
ΔHsolution [KF(s)] in glacial acetic acid 35 kJ/mole
The strength of H-bond between F(g) and CH3COOH(g) + 46 kJ/mole
ΔHKFCH3COOH(s)K+(g)+CH3COOHF(g)+734 kJ/mole
Lattice enthalpy of KF(s)+797 kJ/mole

 

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answer is 21.

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Detailed Solution

ΔHsoO(KFn+ΔHvap+LE+ΔHnyd=Δ

 35ΔHvap +734+46=7973 ΔHvap=35+734+46797+3  DUvap =21kJ/mol

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