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Calomel is mercurous chloride which exist as a dimer. If its molar solubility in water is 10^-2M then its solubility product will be

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8 × 10^–6

4 × 10^–4

4 × 10^–6

4 × 10^–8

answer is A.

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Detailed Solution

Hg₂Cl₂(s) ⇌ Hg₂Cl₂(aq) → Hg₂²⁺(aq) + 2 Cl⁻(aq)
[Hg₂²⁺] = 10⁻², [Cl⁻] = 2×10⁻²

$K_{sp} = (10^{-2}) \times (2\times10^{-2})^{2} = 4\times10^{-6}$ $K$ $sp$ $$ $=$ $($ $10$ $-2$ $)$ $\times$ $($ $2$ $\times$ $10$ $-2$ $)$ $2$ $=$ $4$ $\times$ $10$ $-6$ .

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