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Q.

Carbon cannot be used in the reduction of Al2O3 because :

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a

it is non-metal

b

the heat of formation of CO2 is more than that of Al2O3

c

pure carbon is not easily available

d

the heat of formation of Al2O3 is too high

answer is D.

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Detailed Solution

Carbon cannot be used in the reduction of Al2O3 because the heat of the formation of Al2O3 is too high

The enthalpy of formation is extremely high for alumina.

For the carbothermic reduction to occur, extremely high temperatures of roughly 2100 degrees Celsius are needed.

Due to its high stability and location below carbon's oxidation line in the Ellingham Diagram, aluminium oxide Al2O3 cannot be reduced by carbon due to unfavourable energy conditions.

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