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Q.

Carbon. silicon and germanium have same lattice structure. But charbon is an insulator, silicon and germanium are semiconductors because

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a

number of free electrons for conduction in carbon is negligibly small

b

the bonding electrons exist in first orbit in case of carbon

c

more energy is required for the electron to remove in carbon

d

all the above

answer is D.

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Detailed Solution

The 4 bonding electrons of C, Si or Ge respectively, in the second , third and fourth orbit . Hence , energy required to take out and electron from these atoms (i.e., ionization energy ) will be least for Ge, followed by Si and highest for C. Hence, number of free electrons for conduction in Ge and Si are significant but negligible small for C.

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