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Q.

CaS exists in a cubic close packed arrangement of S2- ions in which Ca2+ ions occupy 1/2 of the available tetrahedral holes. How many Ca 2+and S2- ions are contained in the unit cell?

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a

1, 1

b

2, 4

c

4,4

d

4,2

answer is C.

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Detailed Solution

S2−=8×18+6×12=4  No. of Ca2+=12×8=4

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CaS exists in a cubic close packed arrangement of S2- ions in which Ca2+ ions occupy 1/2 of the available tetrahedral holes. How many Ca 2+and S2- ions are contained in the unit cell?