Q.

 Cd(s)|CdCl2(aq)||AgCl(s)|Ag(s) The cell reaction for the cell is:

Cd(s)+2AgCl(s)2Ag(s)+Cd+2(aq)+2Cl(aq) The standard emf of the cell is 0.6915 V at 0oC and 0.6753 V at 25oC. The ΔH of the redox reaction at 25oC is 

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a

-167.6 kJ

b

+123.5 kJ

c

-234.7 kJ

d

-176 kJ

answer is D.

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Detailed Solution

G0=-nFE0G0=H0-TS0=-nFE0H=TS0-nFE0But, S=nFdE0dTpThe redox reaction involves transaction of 2 electrons(n)H=TnFdE0dTp-nFE0 dE0dTp=0.6753V-0.6915V25=-0.000648=-6.48x10-4H=298K x 2 x 96500C x (-6.48 x 10-4)-2 x 96500 x 0.6753H=-37269-130333=-167602=-167.6kJ 

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