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Q.

 ΔG0 of Cu+(aq) and Cu2+(aq) respectively are +50 and +66 kJ/mole. Value of (ΔH0–TΔS0) for Cu+(aq) → Cu2+(aq) in kilo joules is

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a

-16

b

+116

c

-116

d

+16

answer is D.

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Detailed Solution

ΔG0=ΔHo-TΔSo

ΔG0=ΔGproduct 0-ΔGreactants 0

ΔG0=ΔGCu+20-ΔGCu+0=66-50=+16 K J

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 ΔG0 of Cu+(aq) and Cu2+(aq) respectively are +50 and +66 kJ/mole. Value of (ΔH0–TΔS0) for Cu+(aq) → Cu2+(aq) in kilo joules is