Cell potential of $N i / N i^{2 +} // C l^{-} / C l_{2}, P t$ is highest when
Option [Ni²⁺] [Cl⁻]
1) 10^-1M 10^-1M
2) 10^-2M 10M
3) 10^-2M 10^-2M
4) 10^-1M 10^-2M

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answer is C.

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Detailed Solution

$\begin{array}{l} E_{c e l l} = E_{c e l l}^{0} - \frac{0.0591}{2} \log [N i^{2 +}] {[C l^{-}]}^{2} \\ E_{c e l l} \propto - \log [N i^{2 +}] {[C l^{-}]}^{2} \end{array}$

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