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Certain combinations of cations and anions lead to the formation of coloured salts in solid state even though each of these ions with other counter ions may produce colourless salts. This phenomenon is due to temporary charge transfer between the two ions. Out of the following, the salt that can exhibit this behaviour is :

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${SnCl}_{4}$

${SnBr}_{2}$

${SnCl}_{2}$

${SnI}_{4}$

answer is D.

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Detailed Solution

Due to the high polarisability of $I^{-}$ and due to the high polarising power ${SnI}_{4}$ can exhibit this behaviour.

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