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Q.

Certain metals have a tendency to form compounds which have a "complex structure" and are known as complex. M is a metal with such tendencies and is forming compound like MNH35BrBr2. If it is known that solution of these furnish only those ions which are outside the co-ordination sphere "[ ]" (the bracketed part), then calculate the weight (in g) of AgBr ppt obtained when 1000 g solution of the complex compound containing 40 % by wt. of the complex compound is reacted with 1000 g solution of AgNO3 containing 17 % AgNO3 by weight.
[Atomic weight of M = 75 ]

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answer is 188.

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Detailed Solution

MNH35BrBr2  +  2AgNO32AgBr

n=1000×40100×1400  n=17100×1000170

=1  =1                1 mole         (LR)                 =188g

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