Q.

CH2ClCH2Cl alc. KoH ANaNH2B dil. H2SO4HgSO4,600CC( final ). Functional isomer of ‘C’ is

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a

CH2=CHOH

b

CH3OCH3

c

CH3COCH3

d

CH3CH2OH

answer is B.

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Detailed Solution

Ethylene dichloride upon reaction with alcoholic KOH and sodamide undergoes dehydrohalogenation gives acetylene which on hydrolysis with dilute sulphuric acid dilute mercuric sulphate forms vinyl alcohol which tautomerizes to acetaldehyde.

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