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Q.

CH3-CH2-CH2-COOH 1 moleBr2/Red P A aq. KOH B Conc. H2SO4C.

Common name of ‘C’ is

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a

Crotonic acid

b

Cinnamic acid

c

Valeric acid

d

Malic acid

answer is B.

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Detailed Solution

Organic Chemistry Reaction Sequence

CH3 - CH2 - CH2 - COOH → A → B → C

Step 1: Starting compound is butanoic acid (CH3-CH2-CH2-COOH)

Step 2: Treatment with Br2/Red P (Hell-Volhard-Zelinsky reaction)

  • Alpha bromination occurs at the carbon next to the carboxyl group
  • Product A: CH3-CH2-CHBr-COOH (2-bromobutanoic acid)

Step 3: Treatment with aqueous KOH

  • Nucleophilic substitution replaces Br with OH
  • Product B: CH3-CH2-CH(OH)-COOH (2-hydroxybutanoic acid)

Step 4: Treatment with concentrated H2SO4 with heat

  • Dehydration occurs, forming a double bond
  • Product C: CH3-CH=CH-COOH

Common name of C:Crotonic acid

Crotonic acid is the common name for but-2-enoic acid, an unsaturated carboxylic acid with a double bond between the second and third carbon atoms.

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