Q.

CH3CH2COClBaSO4H2/PdA

Question Image

CH3CH2COOCH3H2O/H+DIBALHE

Correct statements regarding organic products A, B, C, D and E

I)  A, C, D and E are same compounds

II)  A and B are functional isomers

III)  Formation of A is Rosenmund reduction and formation of D is Stephen reaction

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a

Only I

b

Only I and II

c

Only I and III   

d

Only II

answer is C.

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Detailed Solution

Rosenmumd Reaction

CH3CH2COClBaSO4H2/PdCH3CH2CHOA

CH3CH2CNH2O/H+CH3MgBrCH3CH2CHOB

CH3CH2CNH2O/H+DIBALCH3CH2CHOC

Stephen reaction

CH3CH2CNH2O/H+SnCl2+HClCH3CH2CHOD

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