Q.

CH3CH2CH2CONH2 is boiled with aqueous NaOH, then the reaction mixture is acidified with HCl. Products obtained are

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a

CH3CH2CH2COOH + NH4Cl

b

CH3CH2CH2COO- + NH4Cl

c

CH3CH2CH2COONa + NH3

d

CH3CH2CH2COO- + NH3

answer is C.

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Detailed Solution

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Chemical Reaction

The following reaction demonstrates the hydrolysis of an amide to a carboxylic acid and ammonium chloride:

CH3CH2CH2CONH2 + NaOH → CH3CH2CH2COO- ∆
CH3CH2CH2COO- + HCl → CH3CH2CH2COOH + NH4Cl

Steps:

  1. The amide (CH3CH2CH2CONH2) is hydrolyzed in the presence of NaOH under heat (), forming the carboxylate ion (CH3CH2CH2COO-).
  2. The carboxylate ion reacts with HCl to form the carboxylic acid (CH3CH2CH2COOH) and ammonium chloride (NH4Cl).
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