Q.

CH3CH2Clalc.KCNAmajor correct statements are (B is the minor product)

A) A on hydrolysis given propanoic acid 

B) A on partial hydrolysis gives propanamide

C) A on reduction with LiACH4 (or) Na/C2H5OH (or) H2/Pt gives 1-propanamine

D) B in presence of NaHg/C2H5OH (or) H2/Cal gives N-methyl Ethanamine

E) B on hydrolysis gives Ethanamine and methanoic acid

F) A and B are functional isomers

 

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a

All are correct

b

A, B, D, E, F only

c

A, B, C, D, E only

d

A, C, D, E only

answer is A.

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Detailed Solution

CH3CH2CNmajorCH3CH2NCminor

ionic Cu acids like KCN & NaCN with RX gives RCN on major produce 

CH3CH2CNAH+orOHH2OCH3CH2CONH2AmideH+orOHH2OCH3CH2COOHCarboxylic acid

CH3CH2CAN+4HNaC2H5OHLiACH4orCH3CH2CH2NH2

CH3CH2NB¯¯C+HorH2/catNaHg/C2H5OHCH3CH2NHCH3 

CH3CH2NCB+H2OH+CH3CH2NH2+HCOOH

RCN & RNC are functional isomers All are correct

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