Q.

CH3CH2NH2 contains a basic NH2 group, but CH3CONH2 does not, because.

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a

In CH3CH2NH2 there is no resonance, while in acetamide the lone pair of electron on N-atom is delocalized and therefore less available for protonation

b

In CH3CH2NH2 the electron pair on N-atom is delocalized by resonance

c

None of these

d

Acetamide is amphoteric in character

answer is C.

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Detailed Solution

CH3-CH2-NH2 is the chemical formula of ethyl amine and CH3CONH2 is the chemical formula of acetamide. In acetamide, the CH3 group attached to the C=O shows inductive effect and it undergoes resonance hence increasing its stability which does not happen in the case of ethyl amine. Due to resonance, less number of electrons are available for donation so, it is less basic than ethylamine.

Therefore, option (C) is correct.

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