Q.

CH3CH2OHPCC X ;   CH3CH2OHCrO3+H2SO4 Y ;  X and Y respectively are

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a

Aldehyde ; Aldehyde

b

Aldehyde ; Ketone

c

Carboxylic acid ; Carboxylic acid

d

Aldehyde ; Carboxylic acid

answer is D.

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Detailed Solution

PCC is useful in controlled oxidation. Primary alcohols give aldehydes;

X is CH3-CHO;

CrO3+H2SO4 is Jone's reagent. It oxidizes primary alcohols to carboxylic acids;

Y is CH3-COOH ;

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CH3CH2OH→PCC X ;   CH3CH2OH→CrO3+H2SO4 Y ;  X and Y respectively are