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Q.

CH3CH=CH2+NOClP. Identify the product 

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a

CH3CHlCH2l              NO    CI

b

                         NO CH3CH2  CHll                          CI              

c

CH2lCH2  CH2l   NO                   Cl    

d

CH3CHlCH2l             Cl       NO 

answer is A.

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Detailed Solution

  • CH3CHpropylene=CH2+NO- Cl+ CH3CHlCH2l                                                               Cl       NO                                                    propylene nitroso chloride
  • This reaction is an example of electrophilic addition reaction and in it addition takes place according to Markovnikov rule. ("Negative part of additive reagent adds to less hydrogenated or more substituted carbon atom of double bond of unsymmetrical alkene").
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