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Q.

CH3CH=CH2PeroxideHClAdry  etherNaB. ‘A’ and ‘B’ in the above sequence of reactions are respectively

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a

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b

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c

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d

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answer is D.

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Detailed Solution

HCl does not show peroxide effect and even in the presence of peroxide it follows Markovnikov's rule.

CH3-CH=CH2+HClperoxideCH3-CH(Cl)-CH3A

Two molecules of A undergoes Wurtz reaction in the presence of Na/ether and forms a long chain of alkane

2CH32CHCl Na/dry ether CH32CH-CHCH32B+2NaCl

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