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Q.

CH3I + C2H5O-Na+  A Conc. HI B+C.  ‘B’ and ‘C’ in this reaction are

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a

CH3I and C2H5I

b

CH3OH and C2H5I

c

CH3OH and C2H5OH

d

CH3I and C2H5OH

answer is D.

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Detailed Solution

A = CH3-O-C2H5 ........ Williamson synthesis B = CH3I C = C2H5OH

When a mixed ether (containing 1o and 2o alkyl groups) is heated with conc. HI, the product contains alkyl iodide in which the halo group goes with smaller alkyl group.

The mechanism of the reaction is SN2.

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