Q.

Chemical formula of Hinsberg’s reagent is

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a

C6H5NHSO2C6H5

b

C6H5NHCOC6H5

c

C6H5SO3H

d

C6H5SO2Cl

answer is C.

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Detailed Solution

Hinsberg’s reagent is used to differentiate between primary, secondary and tertiary amines. The chemical name of Hinsberg’s reagent is Benzene sulphonyl chloride. The chemical formula of Benzene sulphonyl chloride is C₆H₅SO₂Cl

Hinsberg’s reagent is used to differentiate between primary, secondary and tertiary amines. The chemical name of Hinsberg’s reagent is Benzene sulphonyl chloride. The chemical formula of Benzene sulphonyl chloride is C6H5SO3H.

Hinsberg reagent is an organic compound with the chemical formula C₆H₅SO₂Cl, also known as benzenesulfonyl chloride. This reagent is widely used in organic chemistry to differentiate between primary, secondary, and tertiary amines.

Definition of Hinsberg Reagent

Hinsberg reagent is an organic compound called benzenesulfonyl chloride, with the chemical formula C₆H₅SO₂Cl. It is a sulfonyl halide used in organic chemistry to test and differentiate between primary, secondary, and tertiary amines.

Chemical Composition

The chemical structure of Hinsberg reagent consists of a benzene ring bonded to a sulfonyl group (-SO₂) and a chlorine atom (-Cl).

  • Chemical formula of Hinsberg’s reagent is: C₆H₅SO₂Cl.
  • Chemical name of Hinsberg reagent is: benzenesulfonyl chloride.

Purpose of Hinsberg Reagent

Hinsberg reagent is used to distinguish between:

  1. Primary amines – React to form sulfonamides that are soluble in alkali.
  2. Secondary amines – Form sulfonamides that are insoluble in alkali.
  3. Tertiary amines – Do not react with the reagent.

This ability to identify the type of amine makes it a valuable tool in organic synthesis and analysis.

Mechanism of Action

The reaction involves nucleophilic substitution:

  1. The amine acts as a nucleophile and attacks the sulfur atom in the sulfonyl chloride group, displacing the chlorine atom.
  2. Primary amines form sulfonamides with an acidic hydrogen, which dissolves in alkali.
  3. Secondary amines also form sulfonamides but lack an acidic hydrogen, making them insoluble in alkali.
  4. Tertiary amines cannot react due to the absence of a reactive hydrogen atom.

This process highlights the specific behavior of each type of amine in the presence of Hinsberg reagent.

Applications

  1. Distinguishing amines: The main application is identifying and separating primary, secondary, and tertiary amines in chemical mixtures.
  2. Organic synthesis: Used in reactions requiring sulfonamides as intermediates.
  3. Chemical analysis: Plays a role in testing the purity and type of amines in laboratory settings.
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