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Q.

Chloretone is

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a

(CH3)2C=CCl2

b

CCl3NO2

c

(CH3)2(OH)CCl3

d

CH3COCH2CH2Cl

answer is B.

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Detailed Solution

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Chloretone is a hypnotic compound, known chemically as 1,1,1-Trichloro-2-methyl-2-propanol. It is prepared by the condensation of acetone (CH3COCH3) and chloroform (CHCl3) in the presence of a strong base.

  • Functional groups: Chloretone contains a tertiary alcohol (–OH on a tertiary carbon) and a trichloromethyl group (CCl3).
  • Molecular formula:C4H7Cl3O
  • IUPAC name: 1,1,1-Trichloro-2-methyl-2-propanol
  • Other names: Chlorobutanol, Chlorbutol
  • Applications: Formerly used as a sedative, hypnotic, and preservative. Has antibacterial and antifungal properties, but is rarely used now due to toxicity and safer alternatives.

The reaction to form chloretone is an example of a nucleophilic addition of chloroform to acetone: CH3COCH3 + CHCl3 → (CH3)2C(OH)CCl3

Chloretone is a white crystalline solid with a mild camphor-like odor and has been used in pharmaceuticals and as a preservative.

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