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Q.

Chlorine atom, in its third excited state, reacts with fluorine to form a compound X. The formula and shape of X are

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a

ClF5, pentagonal

b

ClF4, tetrahedral

c

ClF4, pentagonal bipyramidal

d

ClF7, pentagonal bipyramidal

answer is D.

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Detailed Solution

7Cl=1s2,2s2,2p6,3s2,3px2,3py2,3pz1

Cl=1s2,2s2,2p6,3s1,3px1,3py1,3pz1,3d1,3d13d1

                                             (3rd excited state)

Chlorine atom, in its third excited state, reacts with fluorine to form ClF7. Its shape is pentagonal bipyramidal.

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