Q.

Chlorine gas can be produced in the laboratory by the following reaction.
K2Cr2O7+14HCl2KCl+2CrCl3+7H2O+3Cl2 
If 75 g sample of  K2Cr2O7,  with 98% purity is allowed to react with 365 ml of HCI solution having density of 1.2 g/ml and containing 28% HCI by mass, 'x'g of chlorine is produced. The value of 'x' is (Atomic weights of K=39, Cr =52, O = 16, 
Cl =35.5, H =1 )
 

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answer is 51.

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Detailed Solution

 nK2Cr2O7=75×98100294=0.25
and nHCl14=114×365×1.2×2810036.5=0.24
Hence, HCI is a limiting reagent.
Mass of Cl2 produced =3×7114×(0.24×14)  =51.12g
 
 

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