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Q.

Chlorine reacts with hot and concentrated NaOH to produce compounds (X) and (Y). Compound (X) gives white precipitate with silver nitrate solution. The average bond order between Cl and O atoms in compound (Y) is _____.

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answer is 1.67.

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Detailed Solution

6NaOH   +3Cl2 ​→   5NaCl(X)+NaClO3(Y) ​  +3H2O NaCl+AgNO3 ​ →   AgCl(s)↓White ppt +NaNO3

The structure of (Y) is 

solution

The Cl-O bond order = 53= 1.67

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