Q.

Chlorobenzene can be prepared by reacting aniline with

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a

Nitrous acid followed by heating with Cu2Cl2

b

Chlorine in presence of anhydrous AlCl3

c

Chlorine in presence of UV light

d

 HCl and Cu2Cl2

answer is D.

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Detailed Solution

Given data : It is given to identify chlorobenzene can be prepared by reacting aniline with

Explanation

Aniline and nitrous acid can be combined to create chlorobenzene, which is then heated with cupric chloride.The creation of diazonium salt is the initial stage 

In the second step, a chloro group replaces a diazonium group through the Sandmeyer reaction.The chemical reaction is as follows. 

Chlorobenzene can be prepared by reacting aniline with:

Therefore, chlorobenzene can be prepared by reacting aniline with nitrous acid followed by heating with cuprous chloride Hence, the correct option is D, Nitrous acid followed by heating with Cu2Cl2.

Hence , the correct option (D).Nitrous acid followed by heating with Cu2Cl2

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