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Q.

Choose incorrect option(s) for the given reactions:

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a

A(s)+B(g)C(g)+D(g): At equilibrium, if pressure is increased, no effect on equilibrium.

b

X(g)Y(g)+Z(g), if total pressure of the system is decreased at equilibrium, it will shift in forward direction.

c

H2O(g)+CO(g)H2(g)+CO(g); inert gas is added at constant volume at equilibrium, so total pressure will increase and no effect on equilibrium.

d

I2(g)+3Cl2(g)2ICl3(g)+ heat ; if temperature is increased, equilibrium will shift in backward direction but equilibrium constant will not change.

answer is A, D.

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Detailed Solution

(a) At equilibrium, as P↑, reaction moves in backward direction.
(d) Keq depends on T.

Thus, the correct option are A and D.

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