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Q.

Choose incorrect stability order.

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a

[Cr(NH3 )6 ]1+ < [Cr(NH3 )6 ]2+ < [Cr(NH3 )6 ]3+

b

[Cu(NH3)4]2+ < [Cu(en)2]2+ < [Cu(trien)]2+

c

[Fe(H2O)6 ]3+ < [Fe(NO2 )6  ]3+ < [Fe(NH3 )6 ]3+

d

[Co(H2O)6 ]3+ < [Rh(H2O)6 ]3+ < [Ir(H2O)6]3+

answer is B.

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Detailed Solution

  • Increasing stability order:
  • [Cu(NH3)4]2+ < [Cu(en)2]2+ < [Cu(trien)]2+
  • Their formation of entropy increases in the same order, because denticity of ligand increases[Fe(H2O)6 ]3+ < [Fe(NO2 )6  ]3+ < [Fe(NH3 )6 ]3+
  • NO2 is stronger ligand than NH3
    [Co(H2O)6 ]3+ < [Rh(H2O)6 ]3+ < [Ir(H2O)6]3+
  • Zeff value increases from Co3+ to Ir3+
  • [Cr(NH3 )6 ]1+ < [Cr(NH3 )6 ]2+ < [Cr(NH3 )6 ]3+
  • Oxidation state of Cr atom increases from +1 to +3
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