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Q.

Choose the correct options :

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a

Favorable conditions for formation of graphite are high pressure and 1ow temperature from equilibrium diamond (d=3.5g/ml)graphite (d=2.3g/ml);ΔH=1.9kJ/mole

b

For reaction N2O4(g)2NO,(g) degree of dissociation (α) is Kp4P+Kp where P is equilibrium pressure

c

For reaction Cl2(g)+3F^2(g)2ClF3(g);ΔH=329 kJ dissociation of ClF3(g) will be favorable by addition of inert gas at constant pressure

d

Reaction stops at equilibrium (microscopically)

answer is B.

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Detailed Solution

KP=4α21α2 α=KP4P+KP

Addition of inert gas at constant P, increase the volume, thus, forcing the reaction in backward direction.

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