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Q.

Choose the correct order of Ist ionisation energy.

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a

O>N

b

Ne<F

c

Na>Al

d

Mg>Al

answer is D.

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Detailed Solution

Nuclear charge rises, atomic size falls, and ionisation enthalpy rises as we travel through the period. For Al3s23p1 it is necessary to remove an electron from a partially filled 3p orbital. On the other hand, Mg3s2 in the electron in the stable, fully occupied 3s orbital needs to be removed. More energy is needed to remove an electron from a stable, fully filled orbital than from a partially filled orbital. As a result, the ionisation enthalpy for magnesium is higher than that of aluminium. Hence,  the correct order of Ist ionisation energy is Mg>Al.

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