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Q.

Choose the correct statement about Metal Carbonyls:

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a

Decacarbonyl-dimanganese(0) is made up of two square pyramidal Mn(CO)5 units joined by a Mn-Mn bond

b

Octacarbonyl-dicobalt(0) has a Co-Co bond bridged by two CO groups

c

MC π-bond is formed by the donation of a pair of electrons from a filled d-orbital of metal into the vacant antibonding π orbital of carbon monoxide

d

A total of ten MC σ bonds are present in Co2(CO)8 complex

answer is A, B, C, D.

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Detailed Solution

Metal carbonyls are compounds that are highly flammable and have low melting points. Here, Decacarbonyl-dimanganese(0) is made with two square pyramidal Mn(CO)6 units joined by a Mn-Mn bond which is shown below,

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Here, all the options are correct for Metal Carbonyls.

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