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Q.

Choose the correct statement for the complex AlH2O63+:

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a

It has the same hybridisation as TiH2O63+VH2O63+,TiF63and  VH2O62+ 

b

It has different magnetic property as compared to CrNH363+

c

It has same magnetic property as compared to MnF62 but different hybridisation.

d

Both (a) and (b)

answer is B.

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Detailed Solution

Since NH3 is a weak field ligand and, due to d2sp3 hybridizationelectrons in the third orbitals are therefore left unpaired, CrNH363+ has a paramagnetic characteristic. While AlH2O63+ is diamagnetic. Hence, option B is correct. 

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