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Q.

Choose the correct statement from the following :

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a

When KI  is added to Pb(OAc)2  solution produces scarlet red ppt. of PbI2

b

Using AgNO3, acetate and oxalate can be distinguished

c

'AgCl' is insoluble in Na2S2O3 solution

d

Using (conc. H2SO4+MnO2Cl- and Br- can be distinguished

answer is D.

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Detailed Solution

When concentrated sulfuric acid is heated the bromide ion in solid salts can function as a reducing agent, reducing the acid to sulphur dioxide and oxidising the bromide ion to free bromine. The chloride ion in solid salts can operate as an oxidising agent when combined with manganese oxide, reducing sulfuric acid to sulphur dioxide and oxidising the chloride ion to free bromine. Hence from the above, it is observed that using concentrated sulphuric acid and manganese oxide chlorine and bromine ion is distinguished.

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