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Q.

Choose the correct statement(s)

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a

For phase transformation of liquid water at 1 atm, 373 K to water vapour at 1 atm, 373 K, G will be zero.

b

Two solid blocks of same material and same mass having different temperature are kept in an isolated system then entropy of system must increase.

c

Intensive properties are not additive in nature while extensive properties are additive in nature

d

No cyclic process is possible in which the sole  result is absorption of heat from a hot reservoir and its complete conversion into work

answer is A.

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Detailed Solution

All statement are correct

For phase transformation of liquid water at 1 atm, 373 K to water vapour at 1 atm, 373 K, G will be zero.

When two identical solid blocks with differing temperatures are stored in a closed system, the entropy of the system must rise.

While widespread characteristics are cumulative in nature, intensive properties are not.

It is impossible to have a cyclic process where the only outcome is the complete conversion of heat from a hot reservoir into work.

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