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Q.

Choose the halogen which is most reactive towards SN1 reaction in the given compounds (A, B, C and D) 
 

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a

ABr(a);BI(a);CBr(b);DBr(a)

b

ABr(b);BI(a);CBr(a);DBr(a)

c

ABr(b);BI(b);CBr(b);DBr(b)

d

ABr(a);BI(a);CBr(a);DBr(a)

answer is A.

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Reactivity of SN1 depends on stability of carbocation  

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