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Q.

Choose the incorrect statement :

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a

FeSO4 solution mixed with NH42SO4 solution in 1: 1 molar ratio gives the test of Fe2+ ion 

b

CuSO4 solution mixed with aqueous ammonia in 1 : 1 molar ratio gives test of Fe2+ ion 

c

Aq. CuSO4 solution (blue in colour) gives a green precipitate with aqueous potassium fluoride 

d

Aq. CuSO4 solution (blue in colour) gives a bright green solution with aqueous potassium chloride

answer is B.

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Detailed Solution

Since CuSO4 solution mixed with aqueous ammonia in 1: 4 molar ratio gives test of  Cu2+ion statement B is incorrect.

The reaction is having follows,

CuSO4+4NH3CuNH34SO4

Hence, option B is correct.

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