Q.

Choose the reaction(s) from the following options, for which the standard enthalpy of reaction is equal to the standard enthalpy of formation.

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a

18S8(s)+O2(g)SO2(g)

b

2C(gas)+3H2(g)C2H6(g)

c

2H2(g)+O2(g)2H2O(l)

d

32O2(g)O3(g)

answer is C, D.

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Detailed Solution

The standard enthalpy of formation is defined as standard enthalpy change for formation of 1 mole of a substance from its elements, present in their most stable state of aggregation.
 32O2(g)O3(g);
18S8(s)+O2(g)SO2(g) 
In the above two reactions standard enthalpy of reaction is equal to standard enthalpy of formation. 

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