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Q.

Chrome alum is

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a

K2SO4Cr2SO436H2O

b

K2SO4Cr2SO4324H2O

c

K2SO4Cr2SO4318H2O

d

K2SO4Cr2SO4312H2O

answer is D.

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Detailed Solution

K₂SO₄·Cr₂(SO₄)₃·24H₂O

Explanation:

  • Chrome alum, also known as Chromium(III) potassium sulfate, is a type of double sulfate compound.
  • Its chemical formula is KCr(SO₄)₂·12H₂O.
  • The formula indicates the presence of 12 water molecules of crystallization per chromium sulfate unit. When combined with potassium sulfate, the total water molecules of crystallization amount to 24.
  • Therefore, the correct formula aligning with the given options is: K₂SO₄·Cr₂(SO₄)₃·24H₂O.

Additional Details:

  • Classification: Chrome alum belongs to the category of alums, which are double sulfate salts containing a monovalent and a trivalent cation.
  • Properties: It forms dark violet crystals, highly soluble in water.
  • Applications:
    • Used in leather tanning to stabilize collagen fibers.
    • Applied in dyeing processes for its mordant properties.
    • Historically used in photography as a gelatin hardening agent.

Chrome alum is correctly represented as K₂SO₄·Cr₂(SO₄)₃·24H₂O, which matches option d.

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