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Q.

Cinnamic acid (Ph-CH=CH-COOH) is nitrated preferably at........... and it......... is than nitration of benzene.

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a

m-position, faster

b

o and p-positions, faster

c

m-position, slower

d

 o and p -position, slower

answer is D.

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Detailed Solution

Because benzene is an electron-rich species for electrophile reactions, nitration of cinnamic acid yields a mixture of ortho and para nitrocinnamic acids, which slows down the reaction rate with the electrophile. Therefore, benzene nitration proceeds more quickly than cinnamic acid nitration.

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