$C l_{2} (g) + B a {(O H)}_{2} \to X (a q) + B a C l_{2} + H_{2} O; X + H_{2} S O_{4} \to Y + B a S O_{4}; Y \to_{> 365 K}^{Δ} Z + H_{2} O + O_{2}$
$Y, Z$ respectively, and magnetic behavior exhibited by ‘Z’ are

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$H C l O_{4}, C l_{2} O$ diamagnetic

$H C l O_{4}, C l_{2} O_{7}$ diamagnetic

$H C l O_{4}, C l O_{2}$ diamagnetic

$H C l O_{3}, C l O_{2}$ paramagnetic

answer is B.

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Detailed Solution

$\begin{array}{l} C l_{2} + 2 B a {(O H)}_{2} \to B a {(C l O_{3})}_{2} + 5 B a C l_{2} + 6 H_{2} O \\ B a {(C l o_{3})}_{2} + H_{2} S O_{4} \to 2 H C l O_{3} + B a S O_{4} (↓) \\ 2 H C l O_{3} \to_{> 365 K}^{Δ} 2 C l O_{2} + H_{2} O + \frac{1}{2} O_{2} \end{array}$