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Q.

Cl2 is more reactive than l2  but when KCIO3 reacts with I2 ,CI2 is liberated.. why? 

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Detailed Solution

Reaction of chlorate with iodine is a redox reaction and I2 is oxidised.

halogen in positive oxidation state readily gains electrons and undergoes reduction and SRP of ClO3-/Cl2 is greater than IO3-/I2. Thus ClO3- readily under goes reduction while I2 undergoes oxidation

2KClO3+I22KIO3+Cl2

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