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Q.

Cl2 oxidizes thiosulphate ion to sulphate ion whereas I2 oxidizes thosulphate ion to tetra thionate ion. The difference in the product is due to

 

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a

Cl2 is strong reducing agent than I2

b

Cl2 is strong oxidizing agent than I2

c

Cl2 is gas;I2 is solid

d

Both are diatomic

answer is D.

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Detailed Solution

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With Cl2 : change in oxidation state of S is +2 to +4

With l2 : change in oxidation state of S is +2 to +2.5

more the change in oxidation number stronger is the oxidizing agent

Cl2 is stronger oxidizing agent than I2

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