Q.

Cl2disproportionates into ClandClO3 in alkali. What can we conclude ?

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a

Equal no of equivalents of Cl2 involved in oxidation and reduction half reactions  

b

Eq. wt of oxidized chlorine is 7.1

c

Eq. wt of reduced chlorine is 35.5

d

  56th parts of chlorine is reduced 

answer is A.

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Detailed Solution

3Cl2+6OH5Cl+ClO3+3H2O

            5th6parts (5 chlorine out of 6) of chlorine is reduced

            Eq. wt of oxidized chlorine is 7.1

            Eq. wt of reduced chlorine is 35.5

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