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Q.

CN is oxidised by NO3 in presence of acid :

aCN+bNO3+cH+(a+b)NO+aCO2+c2H2O

What are the values of a, b, c in that order :

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a

3, 7, 7

b

3, 10, 10

c

3, 10, 7

d

3,7,10

answer is B.

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Detailed Solution

aCN+bNO3+CH+(a+b)NO+aCO2+c2H2O

Ion Electron method (Oxidation Half )

33H2O+CN+23NO+22+CO22+6H++7e3e+4H++NO32+NO2+2H2O (reduction half) 73CN+7NO3=10NO+3CO2+5H2Oc2=5c=10(a,b,c)(3,7,10)

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